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61.
含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究(英文) 总被引:4,自引:0,他引:4
镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。 相似文献
62.
地幔主要矿物橄榄石[(Mg089Fe011)2SiO4]的相变与深源地震的解释以及俯冲带和周围地幔的相互作用相关. 其中,形核率和长大率是刻画其相变动力学的两个重要参数. 因为实验技术的原因,目前人们还没有基于实验数据给出橄榄石的形核率. 本文首先通过对挤碰物理图像的分析,对边界形核情形的相变动力学理论中表征挤碰程度的无量纲参数进行了修正. 在此基础上,根据已有的实验资料,首次对橄榄石相变的形核率进行了估计. 通过对形核率数据的拟合,可以得到形核率参数K0和γ1/3. 得到两个形核率参数的变化范围分别为K0=55×1021~87×1027s-1·m-2·K-1,γ1/3=0~020 J·m-2,最佳拟合值为:K0=69×1024s-1·m-2·K-1,γ1/3=016 J·m-2. 相似文献
63.
Melt inclusion and host glass compositions from the easternend of the Southwest Indian Ridge show a progressive depletionin light rare earth elements (LREE), Na8 and (La/Sm)n, but anincrease in Fe8, from the NE (64°E) towards the SW (49°E).These changes indicate an increase in the degree of mantle meltingtowards the SW and correlate with a shallowing of the ridgeaxial depth and increase in crustal thickness. In addition,LREE enrichment in both melt inclusions and host glasses fromthe NE end of the ridge are compatible with re-fertilizationof a depleted mantle source. The large compositional variations(e.g. P2O5 and K2O) of the melt inclusions from the NE end ofthe ridge (64°E), coupled with low Fe8 values, suggest thatmelts from the NE correspond to a variety of different batchesof melts generated at shallow levels in the mantle melting column.In contrast, the progressively more depleted compositions andhigher Fe8 values of the olivine- and plagioclase-hosted meltinclusions at the SW end of the studied region (49°E), suggestthat these melt inclusions represent batches of melt generatedby higher degrees of melting at greater mean depths in the mantlemelting column. Systematic differences in Fe8 values betweenthe plagioclase- and the olivine-hosted melt inclusions in theSW end (49°E) of the studied ridge area, suggest that theplagioclase-hosted melt inclusions represent final batches ofmelt generated at the top of the mantle melting column, whereasthe olivine-hosted melt inclusions correspond to melts generatedfrom less depleted, more fertile mantle at greater depths. KEY WORDS: basalt; melt inclusions; olivine; plagioclase; Southwest Indian Ridge 相似文献
64.
西秦岭北缘天水地区关子镇蛇绿岩由变质基性火山岩(斜长角闪片岩)和蛇纹岩、变辉石岩、变辉长岩等构造岩块组成.其中的变质基性火山岩具有N-MORB的地球化学特征,显示关子镇蛇绿岩是洋脊型蛇绿岩残片.对蛇绿岩中的辉长岩进行了LA-ICP-MS锆石U-Pb定年,得到206Pb/238U加权平均年龄为(499.7±1.8)Ma(MSWD=2.2),代表了辉长岩的结晶年龄,表明关子镇蛇绿岩是晚寒武世在西秦岭北缘李子园-关子镇-武山洋盆扩张过程中岩浆活动的产物,代表了东秦岭早古生代商丹古洋盆在西秦岭造山带北缘向西延伸的组成部分. 相似文献
65.
66.
西秦岭天水地区关子镇蛇绿岩锆石LA-ICP-MSU-Pb定年 总被引:19,自引:1,他引:19
秦岭造山带商丹缝合带的西延部分在天水地区以出露的关子镇蛇绿岩为标志,该蛇绿岩的形成时代是探讨秦岭造山带构造格局与演化的关键.在室内外综合研究的基础上,从该蛇绿岩的辉长岩中精选锆石,通过锆石的CL显微图像进行锆石形态学研究,结合U、Th含量特征,证明本次用于定年的锆石为岩浆成因.辉长岩中的锆石LA-ICP-MS定年给出U-Pb年龄为471 Ma±1.4Ma(MSWD=1.03,2σ),代表了辉长岩的结晶时代,也限定了关子镇蛇绿岩的形成时代.结合已有的地质、地球化学研究成果,认为秦岭商丹古洋盆存在的时限至少可延续至470Ma.该年龄的确定为深入研究和认识秦岭造山带古生代的构造格局及其演化提供了新的证据. 相似文献
67.
Alexander N. Krot Michail I. Petaev Shoichi Itoh Timothy J. Fagan Hisayoshi Yurimoto Michael K. Weisberg Matsumi Komatsu Klaus Keil 《Chemie der Erde / Geochemistry》2004,64(3):185-239
Amoeboid olivine aggregates (AOAs) are the most common type of refractory inclusions in CM, CR, CH, CV, CO, and ungrouped carbonaceous chondrites Acfer 094 and Adelaide; only one AOA was found in the CBb chondrite Hammadah al Hamra 237 and none were observed in the CBa chondrites Bencubbin, Gujba, and Weatherford. In primitive (unaltered and unmetamorphosed) carbonaceous chondrites, AOAs consist of forsterite (Fa<2), Fe, Ni-metal (5-12 wt% Ni), and Ca, Al-rich inclusions (CAIs) composed of Al-diopside, spinel, anorthite, and very rare melilite. Melilite is typically replaced by a fine-grained mixture of spinel, Al-diopside, and ±anorthite; spinel is replaced by anorthite. About 10% of AOAs contain low-Ca pyroxene replacing forsterite. Forsterite and spinel are always 16O-rich (δ17,18O∼−40‰ to −50‰), whereas melilite, anorthite, and diopside could be either similarly 16O-rich or 16O-depleted to varying degrees; the latter is common in AOAs from altered and metamorphosed carbonaceous chondrites such as some CVs and COs. Low-Ca pyroxene is either 16O-rich (δ17,18O∼−40‰) or 16O-poor (δ17,18O∼0‰). Most AOAs in CV chondrites have unfractionated (∼2-10×CI) rare-earth element patterns. AOAs have similar textures, mineralogy and oxygen isotopic compositions to those of forsterite-rich accretionary rims surrounding different types of CAIs (compact and fluffy Type A, Type B, and fine-grained, spinel-rich) in CV and CR chondrites. AOAs in primitive carbonaceous chondrites show no evidence for alteration and thermal metamorphism. Secondary minerals in AOAs from CR, CM, and CO, and CV chondrites are similar to those in chondrules, CAIs, and matrices of their host meteorites and include phyllosilicates, magnetite, carbonates, nepheline, sodalite, grossular, wollastonite, hedenbergite, andradite, and ferrous olivine.Our observations and a thermodynamic analysis suggest that AOAs and forsterite-rich accretionary rims formed in 16O-rich gaseous reservoirs, probably in the CAI-forming region(s), as aggregates of solar nebular condensates originally composed of forsterite, Fe, Ni-metal, and CAIs. Some of the CAIs were melted prior to aggregation into AOAs and experienced formation of Wark-Lovering rims. Before and possibly after the aggregation, melilite and spinel in CAIs reacted with SiO and Mg of the solar nebula gas enriched in 16O to form Al-diopside and anorthite. Forsterite in some AOAs reacted with 16O-enriched SiO gas to form low-Ca pyroxene. Some other AOAs were either reheated in 16O-poor gaseous reservoirs or coated by 16O-depleted pyroxene-rich dust and melted to varying degrees, possibly during chondrule formation. The most extensively melted AOAs experienced oxygen isotope exchange with 16O-poor nebular gas and may have been transformed into magnesian (Type I) chondrules. Secondary mineralization and at least some of the oxygen isotope exchange in AOAs from altered and metamorphosed chondrites must have resulted from alteration in the presence of aqueous solutions after aggregation and lithification of the chondrite parent asteroids. 相似文献
68.
Donald G. Isaak Earl K. Graham Jay D. Bass Hong Wang 《Pure and Applied Geophysics》1993,141(2-4):393-414
We present new elasticity measurements on single-crystal fayalite and combine our results with other data from resonance, pulse superposition interferometry, and Brillouin scattering to provide a set of recommended values for the adiabatic elastic moduliC
ij and their temperature variations. We use a resonance method (RPR) with specimens that were previously investigated by pulse superposition experiments. The nineC
ij of fayalite are determined from three new sets of measurements. One set of our newC
ij data is over the range 300–500 K. We believe that the relatively large discrep ncies found in someC
ij are due in large part to specimen inhomogeneities (chemical and microstructural) coupled with differences in the way various techniques sample, rather than only systematic errors associated with experimental procedures or in the preparations of the specimens.Our recommendeaC
ij's (GPa) and (C
ij/T)
p
(GPa/K) are:
The resulting values for the isotropic bulk and shear moduli,K
s and , and their temperature derivatives are:K
s=134(4) GPa; =50.7(0.3) GPa; (K
s/T)
p
=–0.024(0.005) GPa/K; and (/T)
p
=–0.013(0.001) GPa/K. An important conclusion is thatK
s increases as the Fe/(Fe+Mg) ratio in olivine is increased. 相似文献
69.
MATVEEV S.; PORTNYAGIN M.; BALLHAUS C.; BROOKER R.; GEIGER C. A. 《Journal of Petrology》2005,46(3):603-614
Fourier Transform infrared (FTIR) absorption spectra of hydroxylwere measured on olivine phenocrysts from hydrous basaltic meltsthat originated in island-arc tectonic settings. The basalticmelts encompass a wide range of silica activities from orthopyroxene-saturatedhypersthene-normative to nepheline-normative compositions. Theintensities and wavenumber placement of hydroxyl absorptionbands correlate with the degree of silica saturation of theparent melt from which the olivine crystallized. Olivines fromsilica-undersaturated nepheline-normative melts absorb IR radiationin the wavenumber range 34303590 cm1 (Group 1).In contrast, olivines from orthopyroxene-saturated boniniticmelts exhibit hydroxyl absorption bands in the wavenumber range32853380 cm1 (Group 2). Olivines crystallizedat intermediate silica activities exhibit a combination of thetwo groups of hydroxyl IR bands, where the proportion of Group2 bands increases with increasing silica saturation of the parentmelt. The positions of hydroxyl absorption peaks observed herefor natural samples are consistent with previous measurementson experimentally annealed olivines. Thus protonation experimentscan be employed to make spectroscopically dry olivine structuresvisible by IR, yielding information on the silica saturationof the parental magmas. Hydroxyl concentrations in the studiedolivines were estimated to be 12 ppm, corresponding toan olivinemelt partition coefficient of (1·0 ±0·3) x 104. KEY WORDS: nominally anhydrous minerals; olivine; water; mantle; silica activity; melt inclusions 相似文献
70.
The Kundal area of Malani Igneous Suite consists of volcano-plutonic rocks. Basalt flows and gabbro intrusives are associated
with rhyolite. Both the basic rocks consist of similar mineralogy of plagioclase, clinopyroxene as essential and Fe-Ti oxides
as accessories. Basalt displays sub-ophitic and glomeroporphyritic textures whereas gabbro exhibits sub-ophitic, porphyritic
and intergrannular textures. They show comparable chemistry and are enriched in Fe, Ti and incompatible elements as compared
to MORB/CFB. Samples are enriched in LREE and slightly depleted HREE patterns with least significant positive Eu anomalies.
Petrographical study and petrogenetic modeling of [Mg]-[Fe], trace and REE suggest cogenetic origin of these basic rocks and
they probably derived from Fe-enriched source with higher Fe/Mg ratio than primitive mantle source. Thus, it is concluded
that the basic volcano-plutonic rocks of Kundal area are the result of a low to moderate degree (< 30%) partial melting of
source similar to picrite/komatiitic composition. Within plate, anorogenic setting for the basic rocks of Kundal area is suggested,
which is in conformity with the similar setting for Malani Igneous Suite. 相似文献